Coria (Arg, 8 ) – Djokovic (Ser) 4/6 6/2 3/2
Canas (Arg, 9) – Montanes (Esp) 6/1 6/3 6/4
Melzer (Aut) - Youzhny (Rus, 29) 6/3 6/4 7/6
Haas (All, 21) - Spadea (EU) 6/4 6/3 abandon
Davydenko (Rus, 12) - Rochus (Bel) 3/6 7/5 6/2 6/3
Mathieu (Fra) - Guccione (Aus) 6/3 6/4 6/4
Puerta (Arg) - Vliegen (Bel) 6/3 7/5 6/2
Ferrero (Esp, 32) - Hernych (Rtc) 6/4 6/4 6/2
Andreev (Rus) - Nieminen (Fin) 6/2 6/4 6/7 6/2
Wawrinka (Sui) - Blake (EU) 6/7 5/7 6/1 6/3 6/4
Volandri (Ita, 27) - Saretta (Bré) 6/4 6/1 6/2
Safin (Rus, 3) - Dlouhy (Rtc, q) 6/7 6/3 7/5 6/1
Kiefer (All, 28) - Clément (Fra, wc) 4/6 6/2 6/2 4/6 6/4
Acasuso (Arg) - Roddick (EU, 2) 3/6 4/6 6/4 6/3 8/6